One of the tools I use for color theory is this nifty
Color Generator. One of the great things about it is that you can pick complementary, contrasting and mixed colors. It picks colors pretty well. For example,
This color scheme is just fantastic, in my opinion - but I like pastels and more unsaturated tones. It would also fit in with the general scheme you're planning.
And you're right, if you go with a more Tuscan feel, it's mostly golds and reds, with an occasional olive green. However, some of the more modern and ritzier Italian places do use blue quite a bit (like
this one)
So I was thinking a very pale blue and pale green with a vibrant compliment, such as a sharp ...
I'd go with a light and warm brown tone (and you can almost go into orange here for the contrast). It would still be a contrasting color but since it's a fairly neutral color, it would compliment pretty well.
Lastly, if you want more suggestions for the furniture/accessories, here are a few others (well, the little ones that aren't obvious things such as flower pots and such):
- make up, creams and perfume bottles for the vanity
- butter churner, broom, pitcher and pails for the kitchen
- tray for tea/breakfast with little items such as teacups, plates, etc
- soap holder and towel rack for the bathroom (maybe even a hamper for the laundry!)
- poker, shovel and bed warmer for the fireplace
- bowl of fruit, napkin & napkin rings for the dining table
- abacus and stacks of paper/books for the office
Feel free to disregard any of those ideas if they sound silly. But those are just the little details I wish tilesets included sometimes.