Gladiator and Braveheart are tied at #1 on my list. They have been my favourite films ever since they were released. Damn that Ridley Scott and his directing abilities (Gladiator).
Gladiator
Braveheart
House of Flying Daggers
Crouching Tiger Hidden Dragon
Fearless
Hero
Rush Hour
Rush Hour 2
Amadeus
Pirates of the Caribbean (Dead Man's Chest)
Pirates of the Caribbean (Black Pearl)
Short Circuit
Silence of the Lambs (only reason I liked this film is because of Anthony Hopkins)
Hannibal (best film of the series...so far)
Shanghai Noon (Jackie Chan & Owen Wilson. Can't beat that duo)
Shanghai Knights
The Wizard of Oz
The Lion King (not the second or the Pumba and Timone one)
Cinderella (the original version, not the one with Brandy)
The Little Mermaid
Beauty and the Beast
The Emperor's New Groove (Kronk, hahaha)
...and many, many more.